Appendix

Solubility Product Constant

Solubility Product Constants for Select Compounds

Ksp determined at 25 °C.

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Substance

Ksp

Aluminum Compounds

AlAsO4

1.6 × 1016

Al(OH)3 amorphous

1.3 × 1033

AlPO4

6.3 × 1019

Barium Compounds

Ba3(AsO4)2

8.0 × 1015

BaCO3

5.1 × 109

BaC2O4

1.6 × 107

BaCrO4

1.2 × 1010

BaF2

1.0 × 106

Ba(OH)2

5 × 103

Ba3(PO4)2

3.4 × 1023

BaSeO4

3.5 × 108

BaSO4

1.1 × 1010

BaSO3

8 × 107

BaS2O3

1.6 × 105

Bismuth Compounds

BiAsO4

4.4 × 1010

BiOCl

1.8 × 1031

BiO(OH)

4 × 1010

Bi(OH)3

4 × 1031

BiI3

8.1 × 1019

BiPO4

1.3 × 1023

Cadmium Compounds

Cd3(AsO4)2

2.2 × 1033

CdCO3

5.2 × 1012

Cd(CN)2

1.0 × 108

Cd2[Fe(CN)6]

3.2 × 1017

Cd(OH)2 fresh

2.5 × 1014

Calcium Compounds

Ca3(AsO4)2

6.8 × 1019

CaCO3

2.8 × 109

CaCrO4

7.1 × 104

CaC2O4·H2O§

4 × 109

CaF2

5.3 × 109

Ca(OH)2

5.5 × 106

CaHPO4

1 × 107

Ca3(PO4)2

2.0 × 1029

CaSeO4

8.1 × 104

CaSO4

9.1 × 106

CaSO3

6.8 × 108

Chromium Compounds

CrAsO4

7.7 × 1021

Cr(OH)2

2 × 1016

Cr(OH)3

6.3 × 1031

CrPO4·4H2O green§

2.4 × 1023

CrPO4·4H2O violet§

1.0 × 1017

Cobalt Compounds

Co3(AsO4)2

7.6 × 1029

CoCO3

1.4 × 1013

Co(OH)2 fresh

1.6 × 1015

Co(OH)3

1.6 × 1044

CoHPO4

2 × 107

Co3(PO4)2

2 × 1035

Copper Compounds

CuBr

5.3 × 109

CuCl

1.2 × 106

CuCN

3.2 × 1020

CuI

1.1 × 1012

CuOH

1 × 1014

CuSCN

4.8 × 1015

Cu3(AsO4)2

7.6 × 1036

CuCO3

1.4 × 1010

Cu2[Fe(CN)6]

1.3 × 1016

Cu(OH)2

2.2 × 1020

Cu3(PO4)2

1.3 × 1037

Gold Compounds

AuCl

2.0 × 1013

AuI

1.6 × 1023

AuCl3

3.2 × 1025

Au(OH)3

5.5 × 1046

AuI3

1 × 1046

Iron Compounds

FeCO3

3.2 × 1011

Fe(OH)2

8.0 × 1016

FeC2O4·2H2O§

3.2 × 107

FeAsO4

5.7 × 1021

Fe4[Fe(CN)6]3

3.3 × 1041

Fe(OH)3

4 × 1038

FePO4

1.3 × 1022

Lead Compounds

Pb3(AsO4)2

4.0 × 1036

PbBr2

4.0 × 105

PbCO3

7.4 × 1014

PbCl2

1.6 × 105

PbCrO4

2.8 × 1013

PbF2

2.7 × 108

Pb(OH)2

1.2 × 1015

PbI2

7.1 × 109

PbC2O4

4.8 × 1010

PbHPO4

1.3 × 1010

Pb3(PO4)2

8.0 × 1043

PbSeO4

1.4 × 107

PbSO4

1.6 × 108

Pb(SCN)2

2.0 × 105

Magnesium Compounds

Mg3(AsO4)2

2.1 × 1020

MgCO3

3.5 × 108

MgCO3·3H2O§

2.1 × 105

MgC2O4·2H2O§

1 × 108

MgF2

6.5 × 109

Mg(OH)2

1.8 × 1011

Mg3(PO4)2

1023 to 1027

MgSeO3

1.3 × 105

MgSO3

3.2 × 103

MgNH4PO4

2.5 × 1013

Manganese Compounds

Mn3(AsO4)2

1.9 × 1029

MnCO3

1.8 × 1011

Mn2[Fe(CN)6]

8.0 × 1013

Mn(OH)2

1.9 × 1013

MnC2O4·2H2O§

1.1 × 1015

Mercury Compounds

Hg2Br2

5.6 × 1023

Hg2CO3

8.9 × 1017

Hg2(CN)2

5 × 1040

Hg2Cl2

1.3 × 1018

Hg2CrO4

2.0 × 109

Hg(OH)2

2.0 × 1024

Hg2I2

4.5 × 1029

Hg2SO4

7.4 × 107

Hg2SO3

1.0 × 1027

Hg2(OH)2

2.0 × 1024

Hg(OH)2

3.0 × 1026

Nickel Compounds

Ni3(AsO4)2

3.1 × 1026

NiCO3

6.6 × 109

2 Ni(CN)2 ⇌ Ni2+ + Ni(CN)42

1.7 × 109

Ni2[Fe(CN)6]

1.3 × 1015

Ni(OH)2 fresh

2.0 × 1015

NiC2O4

4 × 1010

Ni3(PO4)2

5 × 1031

Silver Compounds

Ag3AsO4

1.0 × 1022

AgBr

5.0 × 1013

Ag2CO3

8.1 × 1012

AgCl

1.8 × 1010

Ag2CrO4

1.1 × 1012

AgCN

1.2 × 1016

Ag2Cr2O7

2.0 × 107

Ag4[Fe(CN)6]

1.6 × 1041

AgOH

2.0 × 108

AgI

8.3 × 1017

Ag3PO4

1.4 × 1016

Ag2SO4

1.4 × 105

Ag2SO3

1.5 × 1014

AgSCN

1.0 × 1012

Strontium Compounds

Sr3(AsO4)2

8.1 × 1019

SrCO3

1.1 × 1010

SrCrO4

2.2 × 105

SrC2O4·H2O§

1.6 × 107

Sr3(PO4)2

4.0 × 1028

SrSO4

3.2 × 107

SrSO3

4 × 108

Tin Compounds

Sn(OH)2

1.4 × 1028

Sn(OH)4

1 × 1056

Zinc Compounds

Zn3(AsO4)2

1.3 × 1028

ZnCO3

1.4 × 1011

Zn2[Fe(CN)6]

4.0 × 1016

Zn(OH)2

1.2 × 1017

ZnC2O4

2.7 × 108

Zn3(PO4)2

9.0 × 1033

From Patnaik, P., Dean's Analytical Chemistry Handbook, 2nd ed. New York: McGraw-Hill, 2004, Table 4.2.
No metal sulfides are listed in this table because sulfide ion is such a strong base that the usual solubility product equilibrium equation does not apply. See Myers, R. J. Journal of Chemical Education, Vol. 63, 1986, pp. 687-690.
From Meites, L. Ed. Handbook of Analytical Chemistry, 1st ed. New York: McGraw-Hill, 1963.
§Because [H2O] does not appear in equilibrium constants for equilibria in aqueous solution in general, it does not appear in the Ksp expressions for hydrated solids.

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